姓名

孟祥太

性别

男

出生年月

1979.04

学历学位

博士

职称

教授

系别

应用化学系

导师类型

硕导

电话

13602030086

Email

xtmeng@tjut.edu.cn

办公/

科研室

19号楼411室

硕导所属学科

081704 应用化学100701 药物化学

研究

方向

1. 有机小分子催化的串联反应研究

2. 鸟嘌呤核苷衍生物的合成以及自组装性质研究

3. 过渡金属催化的C-H键活化反应的研究

讲授

课程

有机化学， 绿色化学与生活

主要科研项目及代表性成果(包括鉴定项目、论文、专著、获奖、专利等)：

项目:

 1. 鸟嘌呤核苷G-四链体调控π共轭分子的自组装及光物理性能研究（编号：21403154），   国家自然科学基金 （2015.1-2017.12）， 25万，   主持人

2.苝二酰亚胺取代鸟苷的合成及自组装性质研究   （编号： 13JCYBJC38700）， 天津市自然科学基金一般项目 (2013.10-2016.9)， 10万， 主持人

3.：基于C-H键活化的C8取代鸟嘌呤新合成方法研究 (编号：20120502)，天津市高等学校科技发展基金计划项目(2012.11-2014.10)，4万元，主持人。

论文:

(1) Wenhuan   Ding, Youquan Zhang, Aimin Yu, Lei Zhang, and Xiangtai Meng* Substrate-Controlled   Domino Reactions of Crotonate-Derived Sulfur Ylides: Synthesis of   Benzothiophene Derivatives J. Org. Chem. 2018, 83,   13821-13833.

(2) Jinhui   Shen, Yang Yang, Xiaoli Hou, Wenlei Zeng, Aimin Yu, Xiaowei Zhao and Xiangtai   Meng* Darzens reaction of thioisatins and sulfonium salts: approach to the synthesis   of thiochromenone derivatives with anticancer potency     Org.   Biomol. Chem. 2018, 16, 3487-3494.

(3) Shanshan Ma, Aimin Yu* and Xiangtai Meng* Phosphine-catalyzed [4   + 2] annulation of γ-benzyl allenoates: facile synthesis of benzothieno[3,2-b]pyran   derivatives Org. Biomol. Chem. 2018, 16,   2885-2892.

(4) Shanshan   Ma, Aimin Yu, Lei Zhang, and Xiangtai Meng* Phosphine-Catalyzed Domino   Reaction of Thioaurones and Allenoate: Synthesis of Benzothiophene-Fused   Dioxabicyclo[3.3.1]nonane Derivatives J. Org. Chem. 2018, 83,   5410-5419.

(5) Ke Li, Aimin Yu, and Xiangtai Meng* Synthesis of   Dibenzothiophene and 1,4-Dihydrodibenzothiophene Derivatives via Allylic   Phosphonium Salt Initiated Domino Reactions Org. Lett. 2018,   20, 1106-1109.

(6) Jiru   Jia, Aimin Yu,* Shanshan Ma, Youquan Zhang, Ke Li, and Xiangtai Meng*   Solvent-Controlled Switchable Domino Reactions of MBH Carbonate: Synthesis of   Benzothiophene Fused α-Pyran, 2,3-Dihydrooxepine, and Oxatricyclodecene   Derivatives Org. Lett. 2017, 19, 6084-6087.

(7) Youquan Zhang, Aimin Yu, Jiru Jia, Shanshan Ma, Ke Li, Yin Wei*   and Xiangtai Meng* NaH promoted [4 + 3] annulation of crotonate-derived   sulfur ylides with thioaurones: synthesis of 2,5-dihydrobenzo[4,5]thieno[3,2-b]oxepines   Chem. Commun. 2017, 53, 10672-10675.

(8) Yanlong Du, Aimin Yu,* Jiru Jia, Youquan Zhang and Xiangtai   Meng* Direct N-H/α,α,β,β-C(sp³)-H functionalization of piperidine   via an azomethine ylide route: synthesis of spirooxindoles bearing   3-substituted oxindoles Chem. Commun. 2017, 53,   1684-1687.

(9) Yanlong   Du, Aimin Yu, Youquan Zhang, Jiru Jia, Prof. Xiangtai Meng* Cs₂CO₃-Promoted   Michael Addition-[2,3]-Sigmatropic Rearrangement Domino Reaction: Facile   Synthesis of a 3-Substituted Indoles Bearing a Homoallyl Sulfide Moiety Asian J. Org. Chem. 2016,   5, 1309-1313.

(10) Yufen Liu, Yanlong Du, Aimin Yu,* Haifeng Mu and Xiangtai Meng* DABCO-catalyzed   unusual [4 + 2] cycloaddition reaction: non-substituted allenoate acts as a   four-carbon synthon and facile synthesis of spirooxindoles Org. Biomol.   Chem. 2016, 14, 1226-1230.

(11)   Yufen Liu, Yanlong Du, Aimin Yu,* Dabin Qin, Xiangtai Meng* Diverse synthesis   of pyrano[2,3-b]indol and dihydropyrano[2,3-b]indol via tunable   Lewis bases catalyzed domino reactions Tetrahedron, 2015,   71, 7706-7716.

(12)   Yanlong Du, Yufen Liu, Aimin Yu, Dabin Qin, Kui Zhang and   Xiangtai Meng* A Catalyst-Free Approach to Construct   3-(Cyclopentenone)oxindoles Through a Phosphine-Ylide-Initiated Triple Domino   Sequence Asian J. Org. Chem. 2015, 4, 630-637.

(13) Yufen Liu, Qi Zhang,   Yanlong Du, Aimin Yu,* Kui   Zhang and Xiangtai Meng*   Convenient synthesis of substituted tetrahydrofuran via Lewis base catalyzed   [3 + 2] domino reactions RSC. Adv. 2014, 4,   52629-52632.

(14)   Qing Xiao, Dr. Xiangtai Meng, Prof. Dr. Motomu Kanai and Prof. Dr. Yoichiro Kuninobu Palladium-Catalyzed C-H Fluorosilylation   of 2-Phenylpyridines: Synthesis of Silafluorene Equivalents Angew.   Chem. Int.Ed. 2014, 53, 3168-3172.

(15)   Xiangtai Meng, Toshiyuki Moriuchi,* Masatoshi Kawahata,   Kentaro Yamaguchi and Toshikazu  Hirao* A G-octamer scaffold via self-assembly   of a guanosine-based Au(I) isonitrile complex for Au(I)-Au(I) interaction Chem.   Commun. 2011, 47, 4682-4684.

(16)   Xiangtai Meng, Toshiyuki Moriuchi,* Norimitsu Tohnai, Mikiji   Miyata, Masatoshi Kawahata,  Kentaro Yamaguchic and Toshikazu Hirao*   Synthesis and assembling properties  of bioorganometallic cyclometalated   Au(III) alkynyls bearing guanosine  moieties Org. Biomol. Chem.   2011, 9, 5633-5636.

(17)   Xiangtai Meng, Toshiyuki Moriuchi,* Yuki Sakamoto, Masatoshi   Kawahata, Kentaro Yamaguchi and  Toshikazu Hirao* La(OTf)₃-mediated   self-organization of guanosine  with an alkynyl-Au(I)PPh₃   moiety to induce Au(I)-Au(I)  interactions Rsc. Adv., 2012,   2, 4359-4363.

(18)    Xiangtai Meng, Peizhong Xie, You Huang* and Ruyu Chen   Organocatalytic domino reaction of salicyl N-thiophosphoryl imines and methyl   vinyl ketone initiated by an  aza-MBH reaction with bifunctional   phosphine catalysts Rsc. Adv., 2012, 2, 8104-8109.

(19)   Xiang-Tai Meng,*  Rong-Hua Xu, Qing-Shan Li,* Feng-Bo Xu*   Gold(I) and silver(I) complexes of a  diphosphine analog of a   half-calix[4]arene moiety Polyhedron, 2013, 50, 502-506.

(20)   Peizhong Xie, You Huang,* Wenqing Lai, Xiangtai Meng and Ruyu   Chen Bifunctional  phosphine-catalyzed cross-Rauhut-Currier/Michael/aldol   condensation triple  domino reaction: synthesis of functionalized   cyclohexenes Org. Biomol. Chem. 2011, 9,   6707-6714.

(21)   Naokazu Kano,* Masaki  Yamamura, Xiangtai Meng, Takaharu   Yasuzuka and Takayuki  Kawashima Different coordination modes of   2-(diphenylphosphino)azobenzenes in  complexation with hard and soft   metals Dalton Trans. 2012, 41, 11491-11496.

(22)   Naokazu Kano,* Kazuhide  Yanaizumi, Xiangtai Meng and   Takayuki Kawashima Control of  reactivity of phosphine imides by   intramolecular coordination with an  organoboryl group Heteroat. Chem. 2012, 23, 429-434.

(23)    Xiangtai Meng, You Huang, Hongxia Zhao, Peizhong Xie,   Jianze Ma and Ruyu Chen PPh₃-Catalyzed Domino Reaction: A Facile   Method for the Synthesis of Chroman Derivatives Org. Lett.   2009, 11, 991-994.

(24)   Xiangtai Meng, You  Huang and Ruyu Chen Bifunctional   Phosphine-Catalyzed Domino Reaction: Highly  Stereoselective Synthesis   of cis-2,3-Dihydrobenzofurans from Salicyl  N-Thiophosphinyl Imines and   Allenes Org. Lett, 2009, 11, 137-140.

(25)   Xiangtai Meng, You Huang and Ruyu Chen A Novel Selective Aza-Morita–Baylis–Hillman   (aza-MBH) Domino Reaction and Aza-MBH Reaction of N-Sulfonated Imines with   Acrolein  Catalyzed by a Bifunctional Phosphine Organocatalyst Chem.   Eur. J. 2008, 14, 6852-6856.

(26)   Xiang-Tai Meng, Qing-Shan Li, Feng-Bo Xu, Hai-Bin Song,   Christopher E. Anson, and Zheng-Zhi Zhang Extended Calix[4]arene Analogues by   Two P-CuI-P Bridges and Anion  Encapsulation Inorg. Chem. 2006,   45, 7986-7987.